{"id":11,"date":"2022-03-24T14:36:02","date_gmt":"2022-03-24T14:36:02","guid":{"rendered":"http:\/\/domain0bb0cd.tekeez.cloud\/?page_id=11"},"modified":"2023-07-21T12:50:57","modified_gmt":"2023-07-21T11:50:57","slug":"publications","status":"publish","type":"page","link":"https:\/\/thebrowneresearchgroup.co.uk\/?page_id=11","title":{"rendered":"Publications"},"content":{"rendered":"
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96<\/strong> – Fluorochemicals from fluorspar via a phosphate-enabled mechanochemical process that bypasses HF<\/strong><\/p>\n

Calum Patel, Emy Andr\u00e9-Joyaux, Jamie A. Leitch, Xabier Mart\u00ednez De Irujo-Labalde, Francesco Ibba, Job Struijs, Mathias A. Ellwanger, Robert Paton, Duncan L. Browne, Gabriele Pupo, Simon Aldridge, Michael A. Hayward, V\u00e9ronique Gouverneur*, Science<\/em>, 2023<\/strong>, 381<\/em>,\n 302-306<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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95<\/strong> – Ammonia Synthesis by Mechanochemistry<\/strong><\/p>\n

Federico Cuccu, Duncan L. Browne*, Andrea Porcheddu* ChemCatChem<\/em>, 2023<\/strong>,  e202300762<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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94<\/strong> – Evolution of Solid Processing Methods in Continuous Flow Technology: Reactive Extrusion<\/strong><\/p>\n

Jamie A. Leitch, Paul Richardson, Duncan L. Browne*, Chimia.<\/em>, 2023<\/strong>, 77<\/em>, 339-345<\/p>\n

[Open Access]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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93<\/strong> – Scalable Solution for Continuous Manufacturing by Mechanochemical-Assisted Synthesis [Book Chapter]<\/strong><\/p>\n

Jamie A. Leitch, Matthew T. J. Williams, Duncan L. Browne, Mechanochemistry and Emerging Technologies for Sustainable Chemical Manufacturing, Chapter 11<\/em>\n , <\/span>2023<\/strong>, pp 241-257<\/span><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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92<\/strong> – Mechanochemical Simmons\u2013Smith cyclopropanation via ball-milling-enabled activation of zinc(0)<\/strong><\/p>\n

Lorenzo Pontini, Jamie A. Leitch * and Duncan L. Browne*, Green Chem<\/em>., 2023<\/strong>, 25<\/em>, 4319-4325<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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91<\/strong> – Nickel-Catalyzed Intramolecular Alkene Difunctionalization by Ball-Milling<\/strong><\/p>\n

Matthew T. J. Williams, Louis C. Morrill*, Duncan L. Browne*, Adv. Synth. Catal.<\/em>, 2023<\/strong>, 365<\/em>, 1477-1484<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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90<\/strong> – Nitrogenated aromatics from chitin<\/strong><\/p>\n

Camila Souza Santos, Renan Rodini Mattioli, Julia Soares Baptista, Vitor H. Menezes da Silva, Duncan L. Browne, Julio Cezar Pastre* Green Chem.<\/em>, 2023<\/strong>, DOI:10.1039\/D3GC00272A<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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89<\/strong> – Advances in synthesis: general discussion<\/strong><\/p>\n

Faraday Discuss.<\/em>, <\/span>\n 2023<\/strong>, <\/span>241<\/em>\n , 150-177<\/span>\n <\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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88<\/strong> – Kinetics and basic understanding: general discussion<\/strong><\/p>\n

Faraday Discuss.<\/em>, 2023<\/strong>, 241<\/em>, 306-340<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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87 <\/strong>– Safety Considerations and Proposed Workflow for Laboratory-Scale Chemical Synthesis by Ball Milling<\/strong><\/p>\n

Ian Priestley*, Claudio Battilocchio, Andrei V. Iosub, Fabien Barreteau, Gavin W. Bluck, Kenneth B. Ling, Katharine Ingram, Maria Ciaccia, Jamie A. Leitch, and Duncan L. Browne*, Org. Process Res. Dev.<\/em> 2023<\/strong>,\n 27<\/em>, 2, 269\u2013275<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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86- Mechanical Activation of Zero-Valent Metal Reductants for Nickel-Catalyzed Cross-Electrophile Coupling<\/strong><\/p>\n

Andrew C. Jones, Matthew T. J. Williams, Louis C. Morrill*, Duncan L. Browne*, ACS Catal.<\/em> 2022<\/strong>, 12<\/em>, 13681\u201313689<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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85 <\/strong>– Challenges Arising from Continuous Flow Olefin Metathesis<\/strong><\/p>\n

Antonio Del Vecchio, Harry R. Smallman, Jennifer Morvan, Tom McBride, Duncan L. Browne*, Marc Maduit*, Angew. Chem. Int. Ed<\/em>, 2022<\/strong>, 61<\/em>, e202209564<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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84<\/strong> – Temperature-Controlled Mechanochemistry for the Nickel-Catalyzed Suzuki-Miyaura-Type Coupling of Aryl Sulfamates via Ball Milling and Twin-Screw Extrusion<\/strong><\/p>\n

Robert R. A. Bolt, Sarah E. Raby-Buck, Katharine Ingram, Jamie A. Leitch*, Duncan L. Browne*, Angew. Chem. Int. Ed.<\/em> 2022<\/strong>, 61<\/em>, e202210508<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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83 <\/strong>– Continuous Flow Generation of Acylketene Intermediates via Nitrogen Extrusion<\/strong><\/p>\n

Harry R. Smallman, Guilherme A. Brancaglion, Julio C. Pastre, Duncan L. Browne*, J. Org. Chem.<\/em> 2022<\/strong>, 87<\/em>, 12297-12305<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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82<\/strong> – Mechanochemical Techniques for the Activation and Use of Zero-Valent Metals in Synthesis<\/strong><\/p>\n

Andrew C. Jones, Jamie A. Leitch, Sarah E. Raby-Buck, Duncan L. Browne, Nat. Synth., <\/em>2022<\/strong>, 1<\/em>, 763-775<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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81 <\/strong>– Electrochemical Deconstructive Functionalization of Cycloalkanols via Alkoxy Radicals Enabled by Proton-Coupled Electron Transfer<\/strong><\/p>\n

Mishra Deepak Hareram, Albara A. M. A. El Gehani, James Harnedy, Alex C. Seastram, Andrew C. Jones, Matthew Burns, Thomas Wirth, Duncan L. Browne, Louis C. Morrill*, Org. Lett. <\/em>2022<\/strong>, 24<\/em>,\n 3890-3895<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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80<\/strong> – Continuous flow mechanochemistry: reactive extrusion as an enabling technology in organic synthesis<\/strong><\/p>\n

Robert R. A. Bolt, Jamie A. Leitch*, Andrew C. Jones, William I. Nicholson, Duncan L. Browne*, Chem. Soc. Rev.<\/em>, 2022<\/strong>, 51<\/em>, 4243-4260<\/p>\n

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79<\/strong> – Mechanochemical Organocatalysis: Do High Enantioselectivities Contradict What We Might Expect?<\/strong><\/p>\n

Matthew T. J. Williams, Louis C. Morrill*, Duncan L. Browne*, ChemSusChem<\/em>, 2022<\/strong>, 15<\/em>, e202102157<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2021<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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78<\/strong> – Ball-Milling-Enabled Reactivity of Manganese Metal<\/strong><\/p>\n

William I. Nicholson, Joseph L. Howard, Giuseppina Magri, Alex C. Seastram, Adam Khan, Robert R. A. Bolt, Louis C. Morrill, Emma Richards, Duncan L. Browne*, Angew. Chem. Int. Ed.<\/em>, 2021<\/strong>, 60<\/em>,\n 23128-23133<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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77<\/strong> – Direct Amidation of Esters by Ball Milling<\/strong><\/p>\n

William I. Nicholson, Fabien Barreteau, Jamie A. Leitch, Riley Payne, Ian Priestley, Edouard Godineau, Claudio Battilocchio*, Duncan L. Browne*, Angew. Chem. Int. Ed.<\/em>, 2021<\/strong>, 60<\/em>, 21868-21874<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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76 <\/strong>– Continuous Flow Z-Stereoselective Olefin Metathesis: Development and Applications in the Synthesis of Pheromones and Macrocyclic Odorant Molecules<\/strong><\/p>\n

Jennifer Morvan, Tom McBride, Idriss Curbet, Sophie Colombel-Rouen, Thierry Roisnel, Christophe Cr\u00e9visy, Duncan L. Browne*, Marc Maduit*, Angew. Chem. Int. Ed<\/em>, 2021<\/strong>, 60<\/em>, 19685-16960<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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75<\/strong> – Solvent-Minimized Synthesis of 4CzIPN and Related Organic Fluorophores via Ball Milling<\/strong><\/p>\n

Jamie A. Leitch*, Harry R. Smallman, Duncan L. Browne*, J. Org. Chem.,<\/em> 2021<\/strong>, 86<\/em>,14095-14101<\/p>\n

[Special Issue: Enabling Techniques for Organic Synthesis]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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74<\/strong> – A Ball-Milling-Enabled Cross-Electrophile Coupling<\/strong><\/p>\n

Andrew C. Jones, William I. Nicholson, Jamie A. Leitch, Duncan L. Browne*, Org. Lett.<\/em>, 2021<\/strong>, 23<\/em>, 6337-6341<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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73 <\/strong>– Formation and utility of reactive ketene intermediates under continuous flow conditions<\/strong><\/p>\n

Harry R. Smallman, Jamie A. Leitch, Tom McBride, Steven V. Ley*, Duncan L. Browne*, Tetrahedron<\/em> 2021<\/strong>, 93<\/em>, 132305<\/p>\n

[Open Access] <\/strong><\/p>\n

[Special Issue: Advances in Continuous Flow Chemistry]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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72<\/strong> – Accessing novel fluorinated heterocycles with the hypervalent fluoroiodane reagent by solution and mechanochemical synthesis<\/strong><\/p>\n

William Riley, Andrew C. Jones, Kuldip Singh, Duncan L. Browne*, Alison M. Stuart* Chem. Commun.<\/em>, 2021<\/strong>, 57<\/em>, 7406-7409<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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71<\/strong> – Mechanoredox Chemistry as an Emerging Strategy in Synthesis<\/strong><\/p>\n

Jamie A. Leitch*, Duncan L. Browne*, Chem. Eur. J.<\/em> 2021<\/strong>, 27<\/em>, 9721-9726<\/p>\n

[Open Access]<\/strong><\/p>\n

[Editorial Showcase]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2020<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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70<\/strong> – Expedient Organocatalytic Aza-Morita\u2013Baylis\u2013Hillman Reaction through Ball-Milling<\/strong><\/p>\n

Matthew T. J. Williams, Louis C. Morrill*, Duncan L. Browne*, ACS Sustainable Chem. Eng<\/em>, 2020<\/strong>, 8<\/em>, 17876-17881<\/p>\n

[Open Access]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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69<\/strong> – A Robust Pd-Catalyzed C\u2013S Cross-Coupling Process Enabled by Ball-Milling<\/strong><\/p>\n

Andrew C. Jones, William I. Nicholson, Harry R. Smallman, Duncan L. Browne*, Org. Lett.<\/em>, 2020<\/strong>, 22<\/em>, 7433-7438<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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68 <\/strong>– Integrated Batch and Continuous Flow Process for the Synthesis of Goniothalamin<\/strong><\/p>\n

Julio C. Pastre*, Phillip R. D. Murray, Duncan L. Browne, Guilherme A. Brancaglion, Renan S. Galaverna, Ronaldo A. Pilli*, Steven V. Ley, ACS Omega<\/em>, 2020<\/strong>, 5<\/em>, 18472-18483<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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67 <\/strong>– Comparison of the Thermal Stabilities of Diazonium Salts and Their Corresponding Triazenes<\/strong><\/p>\n

Christiane Schotten, Samy K. Leprevost, Low Ming Yong, Colan E. Hughes, Kenneth D. M. Harris, Duncan L. Browne*, Org. Process Res. Dev.<\/em>, 2020<\/strong>, 24<\/em>, 2336-2341<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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66<\/strong> – A Mechanochemical Zinc-Mediated Barbier-Type Allylation Reaction under Ball-Milling Conditions<\/strong><\/p>\n

JieXiang Yin, Roderick T. Stark, Ian A. Fallis, Duncan L. Browne*, J. Org. Chem.<\/em>, 2020<\/strong>, 85<\/em>, 2347-2354<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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65<\/strong> – N-Heterocyclic Carbene Acyl Anion Organocatalysis by Ball-Milling<\/strong><\/p>\n

William I. Nicholson, Alex C. Seastram, Saqib A. Iqbal, Benjamin G. Reed-Berendt, Louis C. Morrill*, Duncan L. Browne*, ChemSusChem<\/em>, 2020<\/strong>, 13<\/em>, 131-135<\/p>\n

[Open Acess]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2019<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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64<\/strong> – Manganese-Catalyzed Electrochemical Deconstructive Chlorination of Cycloalkanols via Alkoxy Radicals<\/strong><\/p>\n

Benjamin D. W. Allen, Mishra Deepak Hareram, Alex C. Seastram, Tom McBride, Thomas Wirth, Duncan L. Browne*, Louis C. Morrill*, Org. Lett.<\/em>, 2019<\/strong>, 21<\/em>, 9241-9246<\/p>\n

[Open Access]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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63<\/strong> – A Ball-Milling-Enabled Reformatsky Reaction<\/strong><\/p>\n

Qun Cao, Roderick T. Stark, Ian A. Fallis, Duncan L. Browne*, ChemSusChem<\/em>, 2019<\/strong>, 12<\/em>, 2554-2557<\/p>\n

[Open Access]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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62 <\/strong>– Sulfonamide Synthesis through Electrochemical Oxidative Coupling of Amines and Thiols<\/strong><\/p>\n

Gabriele Laudadio, Efstathios Barmpoutsis, Christiane Schotten, Lisa Struik, Sebastian Govaerts, Duncan L. Browne, Timothy No\u00ebl*, J. Am. Chem. Soc.,<\/em> 2019<\/strong>, 141<\/em>,5664-5668<\/p>\n

[Open Access]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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61 <\/strong>– Exploring the generation and use of acylketenes with continuous flow processes<\/strong><\/p>\n

Renan Galaverna, Tom McBride, Julio C. Pastre, Duncan L. Browne* React. Chem. Eng., <\/em>2019<\/strong>, 4<\/em>, 1559-1564<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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60 <\/strong>– Continuous flow processing as a tool for the generation of terpene-derived monomer libraries<\/strong><\/p>\n

Renan Galaverna, Lucas P. Fernandes, Duncan L. Browne, Julio C. Pastre*, React. Chem. Eng., <\/em>2019<\/strong>\n , <\/span>4<\/em>, 363-367<\/span><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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59<\/strong> – Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation<\/strong><\/p>\n

Jamie L. Carden, Lukas J. Gierlichs, Duncan F. Wass, Duncan L. Browne, Rebecca L. Melen*, Chem. Commun.<\/em>, 2019<\/strong>, 55<\/em>, 318-321<\/p>\n

[Open Access]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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58<\/strong> – Robust Buchwald\u2013Hartwig amination enabled by ball-milling<\/strong><\/p>\n

Qun Cao, William I. Nicholson, Andrew C. Jones, Duncan L. Browne*, Org. Biomol. Chem.<\/em>, 2019<\/strong>, 17<\/em>, 1722-1726<\/p>\n

[Open Access]<\/strong><\/p>\n

[‘New Talent’ Issue]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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57<\/strong> – Switching Chemoselectivity: Using Mechanochemistry to Alter Reaction Kinetics<\/strong><\/p>\n

Joseph L. Howard, Michael C. Brand, Duncan L. Browne*, Angew. Chem. Int. Ed.<\/em>, 2018<\/strong>, 57<\/em>, 16104-16108<\/p>\n

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56 <\/strong>– Immobilized Reagents and Multistep Processes [Book Chapter]<\/strong><\/p>\n

Steven V. Ley, Duncan L. Browne, Matthew O’Brien, Chemistry in Organic Synthesis, Chapter 9<\/em>, 2018<\/strong>, pp 273-312<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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55<\/strong> – Translating solid state organic synthesis from a mixer mill to a continuous twin screw extruder<\/strong><\/p>\n

Qun Cao, Joseph L. Howard, Deborah E. Crawford, Stuart L. James*, Duncan L. Browne*, Green Chem.<\/em>, 2018<\/strong>, 20<\/em>, 4443-4447<\/p>\n

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54<\/strong> – Mechanochemical Activation of Zinc and Application to Negishi Cross-Coupling<\/strong><\/p>\n

Qun Cao, Joseph L. Howard, Emilie Wheatley, Duncan L. Browne*, Angew. Chem. Int. Ed.<\/em>, 2018<\/strong>, 57<\/em>, 11339-11343<\/p>\n

[Open Access]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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53 <\/strong>– A continuous flow-batch hybrid reactor for commodity chemical synthesis enabled by inline NMR and temperature monitoring<\/strong><\/p>\n

Christiane Schotten, Joseph L. Howard, Robert L. Jenkins, Anna Codina, Duncan L. Browne*, Tetrahedron<\/em>, 2018<\/strong>, 74<\/em>, 5503-5509<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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52<\/strong> – Mechanochemistry as an emerging tool for molecular synthesis: what can it offer?<\/strong><\/p>\n

Joseph L. Howard, Qun Cao, Duncan L. Browne*, Chem. Sci.<\/em>, 2018<\/strong>, 9<\/em>, 3080-3094<\/p>\n

[Open Access]<\/strong><\/p>\n

[Highlighted as a ‘Most Read’ Article in Chem. Sci. in 2018]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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51 <\/strong>– A machine-assisted approach for the preparation of follow-on pharmaceutical compound libraries<\/strong><\/p>\n

Christiane Schotten, Lisa G. T. Leist, A. Lisa Semrau, Duncan L. Browne*, React. Chem. Eng.<\/em>, 2018<\/strong>, 3<\/em>, 210-215<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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50<\/strong> – Mechanochemical electrophilic fluorination of liquid beta-ketoesters<\/strong><\/p>\n

Joseph L. Howard, Yerbol Sagatov, Duncan L. Browne*, Tetrahedron<\/em>, 2018<\/strong>, 74<\/em>, 3118-3123<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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49<\/strong> – One-pot multistep mechanochemical synthesis of fluorinated pyrazolones<\/strong><\/p>\n

Joseph L. Howard, William I. Nicholson, Yerbol Sagatov, Duncan L. Browne*, Beilstein J. Org. Chem<\/em>, 2017<\/strong>, 13<\/em>, 1950-1956<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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48<\/strong> – Exploring the C^N^C theme: Synthesis and biological properties of tridentate cyclometalated gold(III) complexes<\/strong><\/p>\n

Sophie J\u00fcrgens, Valeria Scalcon, Natalia Estrada-Ortiz, Alessandra Folda, Federica Tonolo, Christian Jandl, Duncan L. Browne, Maria Pia Rigobello, Fritz, E. K\u00fchn, Angela Casini, <\/span>\n Bioorg. Med. Chem.<\/em>, <\/span>2017<\/strong>\n , <\/span>25, <\/em>5452-5460<\/span><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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47<\/strong> – From Ligand to Phosphor: Rapid, Machine-Assisted Synthesis of Substituted Iridium(III) Pyrazolate Complexes with Tuneable Luminescence<\/strong><\/p>\n

Lara M. Groves, Christianne Schotten, Joseph Beames, James A. Platts, Simon J. Coles, Peter N. Horton, Duncan L. Browne*, Simon J. A. Pope*, Chem. Eur. J.<\/em>, 2017<\/strong>, 23<\/em>, 9407-9418<\/p>\n

[Hot Paper]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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46 <\/strong>– Exploring Multistep Continuous-Flow Hydrosilylation Reactions Catalyzed by Tris(pentafluorophenyl)borane<\/strong><\/p>\n

Lewis C. Wilkins, Joseph L. Howard, Stefan Burger, Louis Frentzel-Beyme, Duncan. L. Browne*, Rebecca L. Melen*, Adv. Synth. Catal.<\/em>, 2017<\/strong>, 359<\/em>, 2580-2584<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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45 <\/strong>– Continuous Flow Processing as a Tool for Medicinal Chemical Synthesis [Book Chapter]<\/strong><\/p>\n

Duncan L. Browne*, Joseph L. Howard, Christiane Schotten, Comprehensive Medicinal Chemistry, 3rd Edition; Volume 1, Elsevier,<\/em> 2017<\/strong>, pp 1-50<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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44 <\/strong>– Continuous flow synthesis of antimalarials: opportunities for distributed autonomous chemical manufacturing<\/strong><\/p>\n

Joseph L. Howard, Christiane Schotten, Duncan L. Browne*, React. Chem. Eng.<\/em> 2017<\/strong>, 2<\/em>, 281-287<\/p>\n

[‘Emerging Investigators’ Issue]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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43<\/strong> – Controlling reactivity through liquid assisted grinding: the curious case of mechanochemical fluorination<\/strong><\/p>\n

Joseph L. Howard, Yerbol Sagatov, Laura Repusseau, Christiane Schotten, Duncan L. Browne*, Green Chem.<\/em>, 2017<\/strong>, 19<\/em>, 2798-2802<\/p>\n

[‘Emerging Investigators’ Issue]<\/strong><\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2016<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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42 <\/strong>– Fluorination Approaches [Book Chapter]<\/strong><\/p>\n

Duncan L. Browne*, Paul Richardson*, Synthetic Methods in Drug Discovery: Volume 2<\/em>, RSC<\/em> 2016<\/strong>, pp 263-370<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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41 <\/strong>– Protected Diazonium Salts: A Continuous-Flow Preparation of Triazenes Including the Anticancer Compounds Dacarbazine and Mitozolomide<\/strong><\/p>\n

Christiane Schotten, Abdul Hadi Adlmairi, Yerbol Sagatov, Martyn Shepherd, Duncan L. Browne*, J. Flow. Chem.<\/em>, 2016<\/strong>, 6<\/em>, 218-225<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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40<\/strong> – Preparation of difluoromethylthioethers through difluoromethylation of disulfides using TMS-CF2H<\/strong><\/p>\n

Joseph L. Howard, Christiane Schotten, Stephen T. Alston, Duncan L. Browne*, Chem. Commun.<\/em>, 2016<\/strong>, 52<\/em>, 8448-8451<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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39<\/strong> – Synthesis of trifluoromethylated isoxazoles and their elaboration through inter- and intra-molecular C\u2013H arylation<\/strong><\/p>\n

Jian-Siang Poh, Cristina Gacia-Ruiz, Andrea Z\u00fa\u00f1iga, Francesca Meroni, David C. Blakemore, Duncan L. Browne*, Steven V. Ley*, Org. Biomol. Chem.<\/em>, 2016<\/strong>, 54<\/em>, 5983-5991<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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38 <\/strong>– A multistep continuous flow synthesis machine for the preparation of pyrazoles via a metal-free amine-redox process<\/strong><\/p>\n

Jian-Siang Poh, Duncan L. Browne*, Steven V. Ley*, React. Chem. Eng.<\/em>, 2016<\/strong>, 1<\/em>, 101-105<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2015<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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37 <\/strong>– Continuous Flow Metathesis for Direct Valorization of Food Waste: An Example of Cocoa Butter Triglyceride<\/strong><\/p>\n

Christiane Schotten, Dorota Plaza, Simone Manzini, Steven P. Nolan, Steven V. Ley, Duncan L. Browne*, Alexei Lapkin*, ACS Sustainable Chem. Eng.<\/em>, 2015<\/strong>, 3<\/em>, 1435-1459<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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36<\/strong> – Flow chemistry<\/strong><\/p>\n

Duncan L. Browne*, Green Process Synth.<\/em>, 2015<\/strong>, 4<\/em>, 253-253<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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35<\/strong> – Discovery of New Metastable Polymorphs in a Family of Urea Co-Crystals by Solid-State Mechanochemistry<\/strong><\/p>\n

Yating Zhou, Fang Guo, Colan E. Hughes, Duncan L. Browne, Thomas R. Peskett, Kenneth D. M. Harris, Crst. Growth Des. <\/em>2015<\/strong>, 15<\/em>, 2901-2907 <\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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34 <\/strong>– Cluster Preface: Progress in Organo-Fluorine Chemistry<\/strong><\/p>\n

Duncan L. Browne*, Synlett<\/em>, 2015<\/strong>, 26<\/em>, 33-35<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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33 <\/strong>– Back Pressure Regulation of Slurry-Forming Reactions in Continuous Flow<\/strong><\/p>\n

Benjamin J. Deadman*, Duncan L. Browne, Ian R. Baxendale, Steven V. Ley, Chem. Eng. Technol.<\/em> 2015<\/strong>, 38, 259-264<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2014<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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32 <\/strong>– Expedient Preparation of Nazlinine and a Small Library of Indole Alkaloids Using Flow Electrochemistry as an Enabling Technology<\/strong><\/p>\n

Mikhail A. Kabeshov, Biagia Musio, Philip R. D. Murray, Duncan L. Browne, Steven V. Ley*, Org. Lett.<\/em>, 2014<\/strong>, 16<\/em>, 4618-4621<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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31 <\/strong>– Reconfiguration of a Continuous Flow Platform for Extended Operation: Application to a Cryogenic Fluorine-Directed ortho-Lithiation Reaction<\/strong><\/p>\n

James A. Newby, D. Wayne Blaylock, Paul M. Witt, Richard M. Turner, Patrick L. Heider, Bashir H. Harji, Duncan L. Browne, Steven V. Ley*, Org. Process Res. Dev.<\/em> 2014<\/strong>, 18<\/em>, 1221-1228<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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30 <\/strong>– Design and Application of a Low-Temperature Continuous Flow Chemistry Platform<\/strong><\/p>\n

James A. Newby, D. Wayne Blaylock, Paul M. Witt, Julio C. Pastre, Marija K. Zacharova, Steven V. Ley*, Duncan L. Browne*, Org. Process Res. Dev.<\/em> 2014<\/strong>, 18<\/em>, 1211-1220<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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29 <\/strong>– Synthesis and Use of a Trifluoromethylated Azomethine Ylide Precursor: Ethyl 1-Benzyl-trans-5-(trifluoromethyl)pyrrolidine-3-carboxylate<\/strong><\/p>\n

Daniel M. Allwood, Duncan L. Browne, Steven V. Ley*, Org. Synth., <\/em>2014<\/strong>, 91<\/em>, 162-174<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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28 <\/strong>– The Trifluoromethylating Sandmeyer Reaction: A Method for Transforming C-N into C-CF3<\/strong><\/p>\n

Duncan L. Browne*, Angew. Chem. Int. Ed.,<\/em> 2014<\/strong>, 53<\/em>, 1482-1484<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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27 <\/strong>– Investigation of a Lithium\u2013Halogen Exchange Flow Process for the Preparation of Boronates by Using a Cryo-Flow Reactor<\/strong><\/p>\n

James A. Newby, Lena Huck, D. Wayne Blaylock, Paul M. Witt, Steven V. Ley, Duncan L. Browne*, Chem. Eur. J. <\/em>2014<\/strong>, 20<\/em>, 263-271.<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2013<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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26 <\/strong>– Flow chemistry syntheses of natural products<\/strong><\/p>\n

Julio C. Pastre, Duncan L. Browne, Steven V. Ley*, Chem. Soc. Rev.,<\/em> 2013<\/strong>, 42<\/em>, 8849-8869<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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25 <\/strong>– Continuous Flow-Processing of Organometallic Reagents Using an Advanced Peristaltic Pumping System and the Telescoped Flow Synthesis of (E\/Z)-Tamoxifen<\/strong><\/p>\n

Philip R. D. Murray, Duncan L. Browne, Julio C. Pastre, Chris Butters, Duncan Guthrie, Steven V. Ley*, Org. Process Res. Dev.<\/em> 2013<\/strong>, 17<\/em>, 1192-1208<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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24 <\/strong>– Scaling Up of Continuous Flow Processes with Gases Using a Tube-in-Tube Reactor: Inline Titrations and Fanetizole Synthesis with Ammonia<\/strong><\/p>\n

Julio C. Pastre, Duncan L. Browne, Matthew O’Brien, Steven V. Ley, Org Process Res. Dev.<\/em> 2013<\/strong>, 17<\/em>, 1183-1191<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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23 <\/strong>– Camera-enabled techniques for organic synthesis<\/strong><\/p>\n

Steven V. Ley*, Richard J. Ingham, Matthew O’Brien, Duncan L. Browne, Beilstein J. Org. Chem.<\/em> 2013<\/strong>, 9<\/em>, 1051-1072<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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22 <\/strong>– Studies of a Diastereoselective Electrophilic Fluorination Reaction Employing a Cryo-Flow Reactor<\/strong><\/p>\n

Keiji Kakayama, Duncan L. Browne, Ian R. Baxendale, Steven V. Ley*, Synlett<\/em>, 2013<\/strong>, 24<\/em>, 1298-1302<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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21 <\/strong>– Continuous Cold without Cryogenic Consumables: Development of a Convenient Laboratory Tool for Low-Temperature Flow Processes<\/strong><\/p>\n

Duncan L. Browne, Bashir H. Harji, Steven V. Ley, Chem. Eng. Technol.<\/em>, 2013<\/strong>, 36<\/em>, 959-967<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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20 <\/strong>– Miniature Mass Spectrometry and On-line Analysis of Flow Chemistry Research<\/strong><\/p>\n

Duncan L. Browne*, <\/em>The Column, <\/em>2013<\/strong>, 96<\/em>, 2-5<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2012<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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19 <\/strong>– Synthesis and Use of a Trifluoromethylated Azomethine Ylide Precursor<\/strong><\/p>\n

Ga\u00ebl Tran, Robin Meier, Lawrence Harris, Duncan L. Browne, Steven V. Ley*, J. Org. Chem.<\/em> 2012<\/strong>, 77<\/em>, 11071-11078<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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18 <\/strong>– Continuous flow reaction monitoring using an on-line miniature mass spectrometer<\/strong><\/p>\n

Duncan L. Browne, Steven Wright, Benjamin J. Deadman, Samantha Dunnage, Ian R. Baxendale, Richard M. Turner, Steven V. Ley, Rapid Commun. Mass Spectrom., <\/em>2012<\/strong>, 26<\/em>, 1999-2010<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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17 <\/strong>– A prototype continuous-flow liquid\u2013liquid extraction system using open-source technology<\/strong><\/p>\n

Matthew O’Brien, Peter Koos, Duncan L. Browne, Steven V. Ley*, Org. Biomol. Chem.<\/em> 2012<\/strong>, 10<\/em>, 7031-7036<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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16 <\/strong>– Flow synthesis using gaseous ammonia in a Teflon AF-2400 tube-in-tube reactor: Paal\u2013Knorr pyrrole formation and gas concentration measurement by inline flow titration<\/strong><\/p>\n

Philippa B. Cranwell, Matthew O’Brien, Duncan L. Browne, Peter Koos, Anastasios Polyzos, Miguel Pe\u00f1a-L\u00f3peza, Steven V. Ley, Org. Biomol. Chem.<\/em>, 2012<\/strong>, 10<\/em>, 5774-5779<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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15 <\/strong>– Continuous-Flow Processing of Gaseous Ammonia Using a Teflon AF-2400 Tube-in-Tube Reactor: Synthesis of Thioureas and In-Line Titrations<\/strong><\/p>\n

Duncan L. Browne, Matthew O’Brien, Peter Koos, Philippa B. Cranwell, Anastasios Polyzos, Steven V. Ley*, 2012<\/strong>, 23<\/em>, 1402-1406<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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14 <\/strong>– Continuous stream processing: a prototype magnetic field induced flow mixer<\/strong><\/p>\n

Peter Koos, Duncan L. Browne, Steven V. Ley*, Green Process Synth.,<\/em> 2012<\/strong>, 1<\/em>, 11-18<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2011<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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13 <\/strong>– Piecing together the puzzle: understanding a mild, metal free reduction method for the large scale synthesis of hydrazines<\/strong><\/p>\n

Duncan L. Browne*, Ian R. Baxendale, Steven V. Ley, Tetrahedron, <\/em>2011<\/strong>, 67<\/em>, 10296-10303<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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12 <\/strong>– A New Enabling Technology for Convenient Laboratory Scale Continuous Flow Processing at Low Temperatures<\/strong><\/p>\n

Duncan L. Browne, Marcus Baumann, Bashir H. Harji, Ian R. Baxendale, Steven V. Ley*, Org. Lett.<\/em> 2011<\/strong>, 13<\/em>, 3312-3315<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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11 <\/strong>– Continuous Flow Processing of Slurries: Evaluation of an Agitated Cell Reactor<\/strong><\/p>\n

Duncan L. Browne, Benjamin J. Deadman, Robert Ashe, Ian R. Baxendale, Steven V. Ley*, Org. Process Res. Dev., <\/em>2011<\/strong>, 15<\/em>, 693-697<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2010<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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10 <\/strong>– On the use of 2-(trimethylsilyl)iodobenzene as a benzyne precursor<\/strong><\/p>\n

James A. Crossley, James D. Kirkham, Duncan L. Browne, Joseph P. A. Harrity, Tetrahedron Lett., <\/em>2010<\/strong>, 51<\/em>, 6608-6610<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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09 <\/strong>– An Alkynyliodide Cycloaddition Strategy for the Construction of Iodoisoxazoles<\/strong><\/p>\n

James A. Crossley, Duncan L. Browne*, J. Org. Chem.,<\/em> 2010<\/strong>, 75<\/em>, 5414-5416<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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08 <\/strong>– Cycloaddition of benzynes and nitrile oxides: synthesis of benzisoxazoles<\/strong><\/p>\n

James A. Crossley, Duncan L. Browne*, Tetrahedron Lett., <\/em>2010<\/strong>, 51<\/em>, 2271-2273<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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07 <\/strong>– Alkyne [3 + 2] Cycloadditions of Iodosydnones Toward Functionalized 1,3,5-Trisubstituted Pyrazoles<\/strong><\/p>\n

Duncan L. Browne, John B. Taylor, Andrew Plant, Joseph P. A. Harrity*, J. Org. Chem., <\/em>2010<\/strong>, 75<\/em>, 984-987<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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06 <\/strong>– Recent developments in the chemistry of sydnones<\/strong><\/p>\n

Duncan L. Browne, Joseph P. A. Harrity*, Tetrahedron, <\/em>2010<\/strong>, 66<\/em>, 553-568<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2009<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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05 <\/strong>– A divergent strategy to the withasomnines<\/strong><\/p>\n

Robert S. Foster, Jianhui Huang, J\u00e9r\u00f4me F. Vivat, Duncan L. Browne, Joseph P. A. Harrity*, Org. Biomol. Chem.,<\/em> 2009<\/strong>, 7<\/em>, 4052-4056<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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04 <\/strong>– Investigation of the Scope and Regiochemistry of Alkynylboronate Cycloadditions with Sydnones<\/strong><\/p>\n

Duncan L. Browne, J\u00e9r\u00f4me F. Vivat, Andrew Plant, Enrique Gomez-Bengoa, Joseph P. A. Harrity*, J. Am. Chem. Soc.<\/em> 2009<\/strong>, 131<\/em>, 7762-7769<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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03 <\/strong>– Cross Coupling of Bromo Sydnones: Development of a Flexible Route toward Functionalized Pyrazoles<\/strong><\/p>\n

Duncan L. Browne, John B. Taylor, Andrew Plant, Joseph P. A. Harrity*, J. Org. Chem.<\/em>, 2009<\/strong>, 74<\/em>, 396-400<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2008<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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02 <\/strong>– A 2-pyrone cycloaddition route to functionalised aromatic boronic esters<\/strong><\/p>\n

Patrick M. Delaney, Duncan L. Browne, Harry Adams, Andrew Plant, Joseph P. A. Harrity*, Tetrahedron<\/em>, 2008<\/strong>, 64<\/em>, 866-873<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2007<\/h1>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n
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01 <\/strong>– A Sydnone Cycloaddition Route to Pyrazole Boronic Esters<\/strong><\/p>\n

Duncan L. Browne, Matthew D. Helm, Andrew Plant, Joseph P. A. Harrity, Angew. Chem. Int. Ed.<\/em>, 2007<\/strong>, 46<\/em>, 8656-8658<\/p>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n <\/div>\n

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2023 96 – Fluorochemicals from fluorspar via a phosphate-enabled mechanochemical process that bypasses HF Calum Patel, Emy Andr\u00e9-Joyaux, Jamie A. Leitch, Xabier Mart\u00ednez De Irujo-Labalde, Francesco Ibba, Job Struijs, Mathias A. Ellwanger, Robert Paton, Duncan L. Browne, Gabriele Pupo, Simon Aldridge, Michael A. Hayward, V\u00e9ronique Gouverneur*, Science, 2023, 381, 302-306 [LINK] 95 – Ammonia Synthesis by Mechanochemistry Federico Cuccu, Duncan […]<\/p>\n","protected":false},"author":1,"featured_media":18,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"page-templates\/full-width-page.php","meta":{"footnotes":""},"_links":{"self":[{"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=\/wp\/v2\/pages\/11"}],"collection":[{"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=11"}],"version-history":[{"count":21,"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=\/wp\/v2\/pages\/11\/revisions"}],"predecessor-version":[{"id":1269,"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=\/wp\/v2\/pages\/11\/revisions\/1269"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=\/wp\/v2\/media\/18"}],"wp:attachment":[{"href":"https:\/\/thebrowneresearchgroup.co.uk\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=11"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}